Yes, under the Persian King Darius, Afghanistan was part of the Persian Empire because of his conquests for expanding the empire.
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The Persian Empire took in Part of: Afghanistan, Arabia, Bulgaria, Greece, India, Pakistan, Russia, and Ukraine. The Persian Empire took in all of: Armenia, Azerbaijan, Georgia, Iraq, Iran, Israel, Jordan, Lebanon, Pakistan, Syria, Turkey, Egypt, Libya.
Libya, Egypt, the Middle East, Central Asia and today's Afghanistan and Pakistan.
Egypt and Libya were part of the Persian Empire.
Egypt was part of the Persian Empire which Alexander the Great conquered.
The Persian Empire stretched from what is today Afghanistan in the east, trough Persia to Asia Minor in the west.