Officially, there were three goddesses that were known of first. They are Hera, Hestia and Demeter.
Actually there are several goddesses that are older than the three sisters. The first goddess created/born would be Anance:
ANANKE (or Anance) was the Protogenos(primeval goddess) of inevitability, compulsion and necessity. She emerged self-formed at the very beginning of time--an incorporeal, serpentine being whose outstretched arms encompassed the breadth of the universe. (see theoi.com)
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Zeus's first child in Greek mythology is Athena, the goddess of wisdom and warfare.
Goddess of Love and BeautyAphrodite was the goddess of love and beauty in Greek mythology.
She is from Greek mythology, but she's not a goddess. She is the wife of Odysseus, hero of The Odyssey.
Venus is the Roman equivelant of Aphrodite, the goddess of love and beauty in Greek Mythology.
No. In Greek mythology, the goddess Athena had no children. She was a virgin goddess.