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You could. The question is why would you? If it's for protection, acrylics are darn near bullet-proof. They're what you'd use to protect something else. If you're using it to create a glossy sheen, you're better off by glazing the painting with gel medium, the stuff acrylics are made of without the pigment (color).

Use gloss and not matte. Matte is just gloss (or gel) with tiny glass beads mixed in to give a more opaque appearance.

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