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Green stains (copper color) that cannot be removed indicate you might have a pH problem.

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Q: How do you get green stains off the pool plaster probably from tree debris?
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Your pH is up but pool is still green?

Ph is up doesn't correlate with a clean pool. The pH needs to be lower to get it clean. And then you need chlorine, probably lots of it to get it clean; try 8 gallons of liquid or 20lbs of tricolor. Trichlor is good for white plaster pools. If you have a colored plaster, it would be better to use Dichlor.