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Personally, i think hot glue gun is, but it really hurts when you burn yourself, so be careful!

Improved answer -There are numerous cements made exactly with polystyrene in mind. Many can be bought at local model or hobby stores.

I prefer to use MEK, which you can only buy if you have an account at a paint dealership.

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Q: What is the best glue to use to stick polystyrene together?
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