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All protons have a positive charge. The antimatter equivelant to the proton, the antiproton, has a negative charge. Every element of matter (hydrogen, helium, etc.) has an equivalent antimatter element (antihydrogen, antihelium, etc.) and just as every element of matter has a proton in its the nucleus (which, again, is positively charged), every corresponding anti-element has an anti-proton in its nucleus (which is negatively charged).

There are also theoretical "hybrid" elements (called exotic elements of atoms) consisting of both matter an antimatter components, such as a proton and antiproton orbitting each other (this is called Protonium).

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