You get pink from mixing equal parts of red with white.
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Primary paint colors are Red, Yellow, and Blue. Mixing any two or all three of these will give you all colors but it helps to have white to tint some colors.
To add vibrance to the color and to add duriblity.
It depends on what color and what time period. Many years ago, red jasper was used to make paint. So was lapis lazuli, limestone, and various other materials, such as berries and burnt wood.
Man made bricks are usually red or black or grey. This is just the way people paint them.
I'm not sure that "colorful" is the appropriate word, since the only color they used was the blue dye from the woad plant.