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It will decrease engine knocking or pinging associated with detonation problems, and will posssibly burn more efficiently.

It can, but if a higher octane fuel reduces or gets rid of engine knock and/or ping, I would recommend taking your vehicle to a mechanic for diagnosis. Moreso, if you have a Check Engine Light on even. It's possible that you have some carbon build up in your fuel system that is causing the knock and ping. As far as the Nitrous Oxide Emissions being reduced from higher octane fuel, I have no idea. But most owner's manuals outline which octane to use, and wouldn't recommend swaying from their recommendation.

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