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yes and it depends on when and how long they were used

Edit:

steel armour was often coated with paint to protect from rust, particularly on the inside. some types of armour, like Brigandine (made of many small plates attached to a fabric body) were tinned by dipping the plates in molten tin, to prevent rust. Other armours were covered to protect it. The classic "shining armour" however, required a lot of maintenance, and when stored away was often coated in a thin film of oil to protect it from rusting.

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