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The difference is in the height and capacity. The 2016 is 1.6mm (hence the 16), and the 2032 is 3.2mm (again, 32). The capacity on the 2016 is only 80mAh, and the 2032 is 200mAh. They are both 3V batteries. So if you replace a 2016 with a 2032 it will work fine, and will last longer, but you need to make sure that it will actually fit in the battery holder since it's twice as thick.

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