Assuming you mean Toledo OH it should take around 8 hours give or take time for traffic. If you go on Google maps and click on the get directions botton it should give you an estimate of how long it will take.
You can fly, take a train, take a bus, or drive from Barcelona to Valencia. Go to the related link and fill in the blanks. They will recommend a driving route if that was what you wished to know.
Maria Fatima Toledo goes by Ftima Toledo.
Rizaldy Valencia goes by Zaldi.
Fabiola Toledo goes by Fabi.
Goya Toledo goes by Goya.
Guillermo Toledo goes by Willy.
Lorenzo Toledo goes by Law.
Ereina Valencia goes by Honey Rockwell.
Between thirteen and fourteen if you drive.
Cristian Toledo goes by Chris Reiben.
He go with Valencia