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This feels cool on your skin because an endothermic reactions is happening. The reactants have less energy than the products as the reaction is absorbing heat from the surroundings. The enthalpy is therefore a positive value. Since it is absorbing heat from the surroundings, your skin feels cool.

Another answer Those liquids evaporate very quickly. As they evaporate, they cool, and you feel the coolness on your skin.

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