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The energy in the food is stored in the form of chemical bonds. When the catabolic reactions occur nutrient molecules like glucose are broken down into smaller molecules and the energy thus released due to the breaking of chemical pond is conserved in the form of ATP. The most classical reaction that occurs is catabolic oxidation of glucose during respiration. Glucose contains 5 single bonds among six carbons that is broken down into six CO2 molecules and the released energy is stored in 38 ATPs.

C6H12O6 + 6 O2 → 6 CO2 + 6 H2O + 38 ATP

Similar kinds of reactions occur with fat molecules also but with different stoichiometry and the end result is same. The energy released by the breaking of bonds is reserved in the form of ATP.

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