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The bread mold Penicillium is a common example of this; penicillium secrete penicillin, a chemical that kills bacteria.

A second example is the black walnut tree (Juglans nigra), which secrete juglone, a chemical that harms or kills some species of neighbouring plants, from its roots.

A third simple example is when sheep or cattle make trails in grass that they trample on, and without realizing, they are killing the grass.

Source: http://en.wikipedia.org/wiki/Biological_interaction#Amensalism

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