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The acceleration from 25kmh to 30kmh is greater.

Acceleration is the rate change in velocity with respect to time (dv/dt). Going from an initial velocity at one point in time to a final velocity at a later point in time, the average acceleration is given by (vf - vi)/(tf -ti), the change in velocity divided by the duration of acceleration. Since going from 25kmh to 30kmh is a change in velocity of 5kmh and going from 96kmh to 100kmh is a change in velocity of 4kmh, and the duration of each is the same, 25 to 30 is the greater acceleration.

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