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I actually asked my chemistry professor this!! It hurts because when you eat food, particularly sweets, the food/sweets become acidic with your saliva and eats away at the enamel. And usually, people who eat a lot of sweets usually feel this pain because the enamel is worn thin (or sometimes its thinned from hard brushing or poor nutrition) and the food/sweets is eating away at the dentin, and later becomes a cavity.

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18y ago

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