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Water is most dense at 4C (around 39F). Any colder or warmer, and the water's density begins to decrease. This is due to the shape and polarity of the water molecules. The very electronegative oxygen and the lone pair make the molecule into the bent shape (v-shape) with O being the "point" of the v. At 4C, these molecules have stacked into and "filled in" the space between the legs of the "V." As it gets colder, the molecules form a lattice that is more rigid in nature, and eventually a solid that is less dense than liquid water (which is why ice floats, rather than sinks, in water). As 4C water gets warmer, the molecules also move out of the space between the legs due to the extra energy and movement included in a higher temperature.

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