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Purple permanganate ion is reduced and almost decolorized (to Mn(II)) by chloride ion in acid solution. Purple permanganate ion is reduced to green manganate ion by chloride ion in basic solution. In neutral chloride solution, there is no reaction.

Source: UW Card Catalog

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Why does benzene decolorize potassium permanganate?

Benzene decolorizes potassium permanganate because it is a reducing agent. Benzene can donate electrons to the permanganate ions, which causes the purple color of the permanganate solution to fade as it is reduced to colorless manganese ions.


Why is permanganate estimation completed in acid solution?

Permanganate estimation is completed in acid solution because in acidic conditions, permanganate (MnO4-) is reduced to colorless manganous ion (Mn2+), allowing for the endpoint to be easily detected once all the substance being titrated has reacted. Additionally, the acid helps stabilize the permanganate solution and prevents premature oxidation.


What is the Reaction of phenol with potassium permanganate?

When phenol reacts with potassium permanganate in an acidic medium, the purple permanganate solution turns colorless as it is reduced to manganese dioxide. This reaction is a redox reaction where phenol is oxidized to benzoquinone.


What happens when zinc dust is added to an acidified solution of potassium permanganate?

When zinc dust is added to an acidified solution of potassium permanganate, a redox reaction takes place. The zinc reduces the permanganate ion, MnO4-, to form colorless manganese ions, while itself getting oxidized to zinc ions. The overall result is that the purple color of the permanganate solution fades as it is reduced.


Why colour changes to pink when mohr's salt solution is added to potassium permanganate solution?

When Mohr's salt solution is added to potassium permanganate solution, a redox reaction occurs where permanganate is reduced to colorless manganese(II) ions. The pink color observed is due to the remaining manganese(VII) ions from the permanganate that form manganese(VII) ions with Mohr's salt.

Related Questions

What are correct regarding the reaction between potassium ferrocyanide and KMnO4 in acidic solution Permanganate ion is the oxidizing agent or Oxidized?

permanganate ion is an oxidising agent and is reduced.


Why does benzene decolorize potassium permanganate?

Benzene decolorizes potassium permanganate because it is a reducing agent. Benzene can donate electrons to the permanganate ions, which causes the purple color of the permanganate solution to fade as it is reduced to colorless manganese ions.


Why is permanganate estimation completed in acid solution?

Permanganate estimation is completed in acid solution because in acidic conditions, permanganate (MnO4-) is reduced to colorless manganous ion (Mn2+), allowing for the endpoint to be easily detected once all the substance being titrated has reacted. Additionally, the acid helps stabilize the permanganate solution and prevents premature oxidation.


What is the Reaction of phenol with potassium permanganate?

When phenol reacts with potassium permanganate in an acidic medium, the purple permanganate solution turns colorless as it is reduced to manganese dioxide. This reaction is a redox reaction where phenol is oxidized to benzoquinone.


Acidified solution potassium permanganate added solution sodium sulfite?

Potassium permanganate and sulfite:2MnO4-(aq) + 5SO32-(aq) + 6H+(aq) --> 5SO42- + 2Mn2+(aq) + 3H2O(l)Note:Potassium and sodium ions do NOT react, they are tribune-ions


What happens when zinc dust is added to an acidified solution of potassium permanganate?

When zinc dust is added to an acidified solution of potassium permanganate, a redox reaction takes place. The zinc reduces the permanganate ion, MnO4-, to form colorless manganese ions, while itself getting oxidized to zinc ions. The overall result is that the purple color of the permanganate solution fades as it is reduced.


Why colour changes to pink when mohr's salt solution is added to potassium permanganate solution?

When Mohr's salt solution is added to potassium permanganate solution, a redox reaction occurs where permanganate is reduced to colorless manganese(II) ions. The pink color observed is due to the remaining manganese(VII) ions from the permanganate that form manganese(VII) ions with Mohr's salt.


What happen if the potassium permanganate solution drop to the water and add of concentrated sulfuric acid?

When potassium permanganate solution is dropped into water, it dissolves and forms a purple solution. If concentrated sulfuric acid is then added, the manganese in potassium permanganate can be reduced to form a colorless compound. This reaction generates heat and can be exothermic. The resulting solution will likely be colorless or have a faint pink hue instead of the original purple color.


Why do permanganate titration should be done in acidic solution?

Permanganate titration should be done in an acidic solution because permanganate ion (MnO4-) is most stable in acidic conditions. In acidic solution, permanganate ion is reduced to manganese(II) ions (Mn2+) during the titration. This reaction helps in accurately determining the concentration of the substance being titrated.


Why colour of ethanol changes when mix with potassium permanganate?

When ethanol is mixed with potassium permanganate, the purple color of the potassium permanganate fades. This is because ethanol reduces the potassium permanganate to form manganese dioxide, which is a brown precipitate. As a result, the overall color of the solution changes from purple to brown.


What is the importance of boiling KMnO4 solution if it is for future use?

If the potassium permanganate solution is prepared from stock solid potassium permanganate, it is important to remove manganese dioxide from the system. MnO2 catalytically decomposes permanganate into oxygen and lower ox. states manganese. Manganese dioxide is insoluble, whereas permanganate is very soluble. Boiling the solution would ensure that all solid permanganate had dissolved, and so little would be lost upon filtering out MnO2 (which remains insoluble at higher temperatures) The remaining solution will have a longer shelf-life due to the absence of the aforementioned decomposition catalyst. If the permanganate solution is required acidic, the use of a small amount of phosphoric acid can be effective. Typically, sulfuric acid is used in combination with permanganate as an acid oxidant. The problem being that sulfuric acid dissolves manganese and thus the catalyst becomes soluble, and difficult to remove. Stock acid solutions of permanganate have far reduced shelf-life. The addition of a small amount of phosphoric acid helps alleviate this. Manganese(ii) oxide reacts with acidified permanganate to form Manganese(iii) cations - these in turn precipitate from solution as manganese(iii)phosphate. Complex ions of manganese(iii) can also form with phosphate, and these partake roles in equilibrium resulting in their further deposition from solution. Once the phosphate complexes are removed by filtration of the hot acidified permanganate solution, the solution has a longer shelf-life.


What happen in the reaction between chlorine and iodine ions?

In the reaction between chlorine and iodine ions, a redox reaction occurs where chlorine ions oxidize iodine ions to form diatomic iodine molecules. The chlorine ions are reduced to form chloride ions. This reaction can be represented as Cl2 + 2I- -> 2Cl- + I2.