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Yes. The calcium in the tub is mainly Calcium Carbonate mixed with a few other mineral salts (copper oxide - give it a greenish hue, etc). CaCO3 reacts readily with acids (bicarb of soda is CaCO3 - mix it with vinegar or lemon juice - in the sink). A stronger acid (car battery acid) would work better and faster but are harder to get hold of and more precautions must be taken.

Also, most dishwasher detergents contain 'limescale removers' which act in much the same way.

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