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http://majarimagazine.com/2008/06/understanding-coal-sample-analysis/
To convert proximate analysis of coal to ultimate analysis, use the Dulong formula as follows: Carbon = 0.75*(fixed carbon + [volatile matter/100]); Hydrogen = 0.06volatile matter; Oxygen = [moisture/100] + 0.3sulfur - carbon - hydrogen; Nitrogen = volatile matter/100 * 0.01. This formula estimates the ultimate analysis (C, H, O, N) from the proximate analysis (moisture, volatile matter, fixed carbon, ash).
The "ultimate" analysis" gives the composition of the biomass in wt% of carbon, hydrogen and oxygen (the major components) as well as sulfur and nitrogen (if any). The carbon determination includes that present in the organic coal substance and any originally present as mineral carbonate. The hydrogen determination includes that in the organic materials in coal and in all water associated with the coal. All nitrogen determined is assumed to be part of the organic materials in coal. The "proximate" analysis gives moisture content, volatile content,consisting of gases and vapors driven off during pyrolysis (when heated to 950 C), the fixed carbon and the ash,the inorganic residue remaining after combustion in the sample and the high heating value (HHV) based on the complete combustion of the sample to carbon dioxide and liquid water. Proximate analysis is the most often used analysis for characterizing coals in connection with their utilization.
ARB (as received basis) refers to the analysis of coal as it is received at the power plant, including the moisture content. GAR (gross as received basis) refers to the analysis of coal without adjusting for moisture content. So, GAR will have a higher value compared to ARB because it does not account for the moisture content that is present in the coal.
ADB stands for Air Dried Basis in coal specification. This term refers to the moisture content of coal after it has been air dried under specific conditions. It is used to standardize coal analysis and compare the energy content of different coal samples.
The Dulong formula in coal analysis is a method used to estimate the calorific value of coal based on its elemental composition. It calculates the gross calorific value (GCV) of coal by multiplying the percentage of carbon, hydrogen, and sulfur by their respective heating values and summing the results. The formula is: GCV (MJ/kg) = 337C + 1442(H - O/8) + 95S, where C, H, O, and S are the percentages of carbon, hydrogen, oxygen, and sulfur in the coal sample, respectively.
To convert proximate analysis of coal to ultimate analysis, use the Dulong formula as follows: Carbon = 0.75*(fixed carbon + [volatile matter/100]); Hydrogen = 0.06volatile matter; Oxygen = [moisture/100] + 0.3sulfur - carbon - hydrogen; Nitrogen = volatile matter/100 * 0.01. This formula estimates the ultimate analysis (C, H, O, N) from the proximate analysis (moisture, volatile matter, fixed carbon, ash).
The "ultimate" analysis" gives the composition of the biomass in wt% of carbon, hydrogen and oxygen (the major components) as well as sulfur and nitrogen (if any). The carbon determination includes that present in the organic coal substance and any originally present as mineral carbonate. The hydrogen determination includes that in the organic materials in coal and in all water associated with the coal. All nitrogen determined is assumed to be part of the organic materials in coal. The "proximate" analysis gives moisture content, volatile content,consisting of gases and vapors driven off during pyrolysis (when heated to 950 C), the fixed carbon and the ash,the inorganic residue remaining after combustion in the sample and the high heating value (HHV) based on the complete combustion of the sample to carbon dioxide and liquid water. Proximate analysis is the most often used analysis for characterizing coals in connection with their utilization.
Proximate analysis includes determining the moisture content, volatile matter, fixed carbon, and ash content of a sample. It provides important information about the composition and energy content of materials such as coal, biomass, and solid waste. These parameters help in understanding the suitability of a material for various applications, such as combustion or conversion to energy.
Coal is graded based on its carbon content and calorific value. Bituminous coal typically has a higher carbon content and energy value compared to anthracite. One way to identify the grade is to conduct proximate and ultimate analysis tests on the coal samples, which can provide detailed information on its composition and quality. Consulting with a coal expert or using specialized equipment can also help determine the grade accurately.
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ARB (as received basis) refers to the analysis of coal as it is received at the power plant, including the moisture content. GAR (gross as received basis) refers to the analysis of coal without adjusting for moisture content. So, GAR will have a higher value compared to ARB because it does not account for the moisture content that is present in the coal.
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