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Young modulus, E, is the ratio between stress and strain. E=Stress/Strain. Then, more the strain value (in %) is high, more the Young Modulus has a lower value.

Vulcanization is the process which create bonds between molecule, thanks to sulphur, peroxyde etc... At the end, the material is only one molecule and can't be melted (thermoset behaviour). As a result, when stress is applied the vulcanized rubber deforms, but upon release of the stress, the article reverts to its original shape.

Thanks to this chemical process, elongation at break is improved, as tensile properties.

The macromolecules of raw rubber are linked together in vulcanized rubber by cross-linked chemical bonds, which form a vulcanisation network.

(This process is called "chemical" 'cause today a physical vulcanization is possible in order to keep a thermoplastic behaviour).

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