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To come up with the electron configuration for Arsenic, you first need to count up how many electrons it has (it will be the same as the atomic number since the charge is neutral)... 18. Then you need to follow the aufbui order and work your way up the orbitals filling them in. 1s takes 2electrons, 2s takes 2 electrons, 2p takes 6 electrons, 3s takes 2 electrons, and lastly 3p takes 6 electrons (total of 18). The order of the orbitals and how many electrons each can take you will just need to memorize or learn some tricks to remember.

You can also just take a short cut and ignore all the orbitals before the row Arsenic is on to show ONLY the valence electrons, ie:

[Ne] 3s2 3p6

If you are still having trouble, http://mymcat.com/wiki/Electron_Configuration, has a lot of examples, including your question.

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