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HCN bond angles around central atom?

Updated: 4/28/2022
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14y ago

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HCN is linear. Both atoms are 180 degrees from one another.

We know carbon has 4 valance electrons. And needs 4 bonds to complete the shell.

Nitrogen has 5 and needs 3 to complete the shell.

Hydrogen has 1 and needs 1 to complete the shell.

So we want an arrangement where all shells are filled...ideally.

We can do this with a single bond from H to C and a triple bond from N to C.

C has no lone pairs...nothing else blocking the way. So we want the other two atoms on the carbon to be as far away from each other as possible...so it's a 180 angle.

This kind of thing is only confusing because of examples like H2O that are bent...but remember the oxygen in H2O has a lone pairs that need to be repelled by other electrons...meaning lone pairs repel each other as well as other atoms and vice versa so you end up with much more difficult angles.

But in this case, it's nice and simple. Linear molecule.

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