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How cyclohexene mignt be formed as a byproduct in the synthesis of cyclohexanone?

One of the common ways to synthesize ketones is by oxidizing secondary alcohols. Cyclohexanone can be easily prepared from cyclohexanol (or hydroxycyclohexane - same thing) by allowing cyclohexanol to react with potassium dichromate (K2Cr2O7) in the presence of acid. However, some of the cyclohexanol will undergo an elimination reaction because of the acid present and form cyclohexene. Your question is a good example of why it is often important to consider how the reactants should be mixed to get the best results. You would not want to add all of the cyclohexanol to the dichromate solution since performing the reaction that way would maximize the percentage of cyclohexene formed. To limit the extent of the competing elimination reaction, one would want to: 1) Look up the oxidation of secondary alcohols to ketones using potassium dichromate in the literature in order to a. determine the amount of acid needed, and don't use more acid than is necessary, and b. try to find the optimum temp. at which to carry out the reaction. The lower the acid concentration, the less cyclohexene that will be formed. 2) Slowly add the alcohol to a rapidly stirring mixture of an aqueous solution of acidified potassium dichromate. 3) An aqueous solution of acidified potassium dichromate will get warm when it is prepared. It would be best to allow it to cool back to room temp. before beginning the reaction. Once the ketone is formed, it will not react further with acidic dichromate because ketones are difficult to oxidize and dichromate is not a strong enough oxidizer.


When two monosaccharides undergo a dehydration synthesis reaction which type of molecule is formed?

When two monosaccharides undergo a dehydration synthesis reaction, a disaccharide molecule is formed. This type of reaction involves the removal of a water molecule, leading to the joining of the monosaccharides through a glycosidic bond.


What is formed when burning hydrogen in air?

When burning hydrogen in air, water vapor is formed as a byproduct. The chemical reaction can be represented as: 2H2 + O2 -> 2H2O.


What type of bond is formed during dehydration synthesis?

A covalent bond is formed during dehydration synthesis, also known as a condensation reaction. This type of bond involves sharing of electrons between atoms, resulting in the formation of larger molecules such as carbohydrates, proteins, and lipids.


What kind of bond is formed in dehydration synthesis?

Dehydration synthesis occurs primarily between organic molecules. Organic molecules are made of almost exclusively nonmetals. Therefore the bond is covalent.

Related Questions

How can cyclohexene be formed as a byproduct in the synthesis of cyclohexanone?

Cyclohexene can be formed as a byproduct in the oxidation of cyclohexanol to cyclohexanone using a strong oxidizing agent like chromic acid. Under certain conditions, cyclohexene can be further oxidized to form cyclohexanone instead of the desired product, resulting in it being a byproduct of the reaction. This undesired side reaction can occur if the reaction conditions are not carefully controlled.


How cyclohexene mignt be formed as a byproduct in the synthesis of cyclohexanone?

One of the common ways to synthesize ketones is by oxidizing secondary alcohols. Cyclohexanone can be easily prepared from cyclohexanol (or hydroxycyclohexane - same thing) by allowing cyclohexanol to react with potassium dichromate (K2Cr2O7) in the presence of acid. However, some of the cyclohexanol will undergo an elimination reaction because of the acid present and form cyclohexene. Your question is a good example of why it is often important to consider how the reactants should be mixed to get the best results. You would not want to add all of the cyclohexanol to the dichromate solution since performing the reaction that way would maximize the percentage of cyclohexene formed. To limit the extent of the competing elimination reaction, one would want to: 1) Look up the oxidation of secondary alcohols to ketones using potassium dichromate in the literature in order to a. determine the amount of acid needed, and don't use more acid than is necessary, and b. try to find the optimum temp. at which to carry out the reaction. The lower the acid concentration, the less cyclohexene that will be formed. 2) Slowly add the alcohol to a rapidly stirring mixture of an aqueous solution of acidified potassium dichromate. 3) An aqueous solution of acidified potassium dichromate will get warm when it is prepared. It would be best to allow it to cool back to room temp. before beginning the reaction. Once the ketone is formed, it will not react further with acidic dichromate because ketones are difficult to oxidize and dichromate is not a strong enough oxidizer.


What is the limiting reactant in synthesis of cyclohexene?

The limiting reactant in the synthesis of cyclohexene is typically the starting material that is present in the smallest amount compared to the stoichiometric ratios in the reaction. It is the reactant that gets completely consumed first, thereby limiting the amount of product that can be formed.


Are proteins formed by dehydration synthesis?

No; they are formed by translation. Carbohydrates are formed by dehydration synthesis.


In the metabolism of protein the byproduct urea is formed in the?

liver


What is a macro molecule formed by?

A macromolecule is formed by dehydration synthesis (condensation reaction).


Are there cis-trans isomers formed when aqueous bromine react with cyclohexene?

Yes, when aqueous bromine reacts with cyclohexene, cis-trans isomers can be formed. The reaction involves the addition of bromine across the double bond, resulting in the formation of a bromonium ion intermediate. The subsequent attack of water on this intermediate can lead to the formation of both cis- and trans-1,2-dibromocyclohexane isomers.


Are covalent bonds formed in dehydration synthesis?

Yes.


When two monosaccharides undergo a dehydration synthesis reaction which type of molecule is formed?

When two monosaccharides undergo a dehydration synthesis reaction, a disaccharide molecule is formed. This type of reaction involves the removal of a water molecule, leading to the joining of the monosaccharides through a glycosidic bond.


Tell you about Preparation of tetra hydro carbazole please?

from phenyl hydazine .cyclohexanone and acetic acid put them in reflux for 30 min then cool in ice bath .filltert and ppt is formed


What type of product is formed from the reaction of an organic acid and an alcohol?

an ester and byproduct is water


Formed during dehydration synthesis or condensation polymerization?

Water