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C4H10 + 13/2O2 ---> 4CO2 + 5H2O

(1) First balance the carbon atoms: There are 4 on the left, so you'll need 4 on the right. So put a 4 in front of CO2

(2) Next balance the hydrogen atoms: there are 10 on the left, so you'll need 10 on the right. Since you have a water molecule, put 5 in front of H2O (5*2 = 10).

(3) Finally balance the oxygen atoms: on the right you have 4*2 (from the carbon dioxide) + 5*1 (from the water) = 8+5 or 13. So you now need 13 atoms of oxygen on the left. So put 13/2 in front of O2 (13/2 * 2 = 13)

(4) Now get rid of the fraction in front of O2 by multiplying all the coefficients by 2, to get your final balanced equation:

2C4H10 + 13O2 ---> 8CO2 + 10H2O

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