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First, you should determine the geometry of the molecule. How many atoms or lone pairs are associated with the central atom? Is the molecular geometry linear, trigonal planar, tetrahedral, etc. Secondly, you need to determine the electronegativity of the atoms bonded together in the molecule. Polarity is all about electronegativity and how tightly bound electrons are to particular atoms in a molecule. Lone pair electrons on the central atom are obviously quite electronegative and should be accounted for as such. Halogens and other extremely electronegative atoms will provide a strong negative charge due to their affinity for electrons. If the molecule is symmetrical it is to be expected to be non-polar, and if it is asymmetrical it would be expected to be polar, but this is not always the case. For instance, a water molecule is symmetrical, but it is polar due to the pull of the lone pair electrons of the oxygen atom.

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Q: How do you determine if a molecule is over all polar or non polar by finding if it a asymmetrical or symmetrical?
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