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Lets look at the molecule 2-butyne. H3C-C=C-CH3. Notice this molecule is symmetrical about a triple bond.

The C-C triple bond in 2-butyne is IR inactive because of the molecule's overall symmetry. For 1-butyne, you would expect to see a weak peak from 2100-2250 (indicative of a C-C triple bond), but you would not expect to see the same for 2-butyne.

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Q: How do you differantiate between 1- butyne 2-butyne in IR?
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