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Physicists and chemists use a standard notation to describe atomic electron configurations. In this notation, a subshell is written in the form nxy, where n is the shell number, x is the subshell label and y is the number of electrons in the subshell. An atom's subshells are written in order of increasing energy - in other words, the sequence in which they are filled (see Aufbau principle below). For instance, ground-state hydrogen has one electron in the s orbital of the first shell, so its configuration is written 1s1. Lithium has two electrons in the 1s subshell and one in the (higher-energy) 2s subshell, so its ground-state configuration is written 1s2 2s1. Phosphorus (atomic number 15), is as follows: 1s2 2s2 2p6 3s2 3p3. For atoms with many electrons, this notation can become lengthy and so the noble gas notation is used. It is often abbreviated by noting that the first few subshells are identical to those of one or another noble gas. Phosphorus, for instance, differs from neon (1s2 2s2 2p6) only by the presence of a third shell. Thus, the electron configuration of neon is pulled out, and phosphorus is written as follows: [Ne]3s2 3p3. An even simpler version is simply to quote the number of electrons in each shell, e.g. (again for phosphorus): 2-8-5. The orbital labels s, p, d, and f originate from a now-discredited system of categorizing spectral lines as sharp, principal, diffuse, and fundamental, based on their observed fine structure. When the first four types of orbitals were described, they were associated with these spectral line types, but there were no other names. The designation gwas derived by following alphabetical order. Shells with more than five subshells are theoretically permissible, but this covers all discovered elements. For mnemonic reasons, some call the s and p orbitals spherical and peripheral.

The order of increasing energy of the subshells can be constructed by going through downward-leftward diagonals of the table above (also see the diagram at the top of the page), going from the topmost diagonals to the bottom. The first (topmost) diagonal goes through 1s; the second diagonal goes through 2s; the third goes through 2p and 3s; the fourth goes through 3p and 4s; the fifth goes through 3d, 4p, and 5s; and so on. In general, a subshell that is not "s" is always followed by a "lower" subshell of the next shell; e.g. 2p is followed by 3s; 3d is followed by 4p, which is followed by 5s, 4f is followed by 5d, which is followed by 6p, and then 7s. This explains the ordering of the blocks in the Periodic Table. A pair of electrons with identical spins has slightly less energy than a pair of electrons with opposite spins. Since two electrons in the same orbital must have opposite spins, this causes electrons to prefer to occupy different orbitals. This preference manifests itself if a subshell with l > 0 (one that contains more than one orbital) is less than full. For instance, if a p subshell contains four electrons, two electrons will be forced to occupy one orbital, but the other two electrons will occupy both of the other orbitals, and their spins will be equal. This phenomenon is called Hund's rule. The Aufbau principle can be applied, in a modified form, to the protons and neutrons in the atomic nucleus (see the shell model of nuclear physics).

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