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there are a couple of methods available. One is to do it with the use of a scale. another method would be to use two graduated beakers. Fill one to the 4 ml line and our it into the other, filling it to the 3 1/2 graduation. the amount left in the beaker would be 1/2 ml for your unmarked syringe.

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Q: How do you measure half a ml without a small marked syringe?
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