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Did you mean 250 mL of 0.15 M Na2CO3? (It's impossible to make a 15 M Na2CO3 solution, as Na2CO3 is not that soluble.) Yes, you can assume that this will be an aqueous solution.

Steps.

1. Calculate the mass of solid Na2CO3 needed.

2. Place this mass of Na2CO3 in the volumetric flask.

3. Add some water and swirl to dissolve the Na2CO3.

4. Carefully add more water until the total volume of solution is 250 mL, as indicated by the line etched on the neck of the volumetric flask.

250 mL x 1 L x 0.15 mol Na2CO3 x 105.99 g Na2CO3 = 4.0 g Na2CO3 needed

........... 1000 mL ......... 1 L ..................1 mol Na2CO3

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