If you wish to test for the presence of halogen in an iodoform, then you must first inject the iodoform with a touch of helium. This helium will make the halogen react and change colors, making it notable in the iodoform.
First: Flame Test or Beilstein Test- Purple Flame
Second: Silver Nitrate Test- formation of silver iodide (AgI), yellow precipitate
note: AgI- light sensitive powder used in photographic emulsions and antiseptic. Scattered in clouds to cause rainfall.
1) Add silver nitrate to the solution that you want to test for halide ions under acidic conditions (apply nitric acid)
2) A precipitate will form
- A white precipitate indicates the presence of chloride ions
- A cream precipitate indicates the presence of bromide ions
- A yellow precipitate indicates the presence of iodide ions
Also, if you add acidified lead (II) nitrate to the unknown solution, a deep yellow precipitate of lead (II) iodide indicates that iodide ions are present.
The nitric acid reacts with other ions that might precipitate with silver nitrate. Doing this first gets these other unwanted precipitates out of the way. If you are testing with Fluoride as your halide remember that silver nitrate does not precipitate with Fluoride, so no precipitate does not mean that halide ions are not present.
halide ions strongly interact with the counter-ions. However, mineral oil is non-polar. To dissolve the halide ions (and the counter-ions) into mineral oil would drastically raise system energy. Thus it does not work. More simply, halide ions have a charge and won't easily dissolve in non-polar substances, since like-dissolves-like.
Ions of the halogen group are called halide ions; their compounds are called halides.
The presence of halide ions
A halide ion is a hydrogen atom with a negative charge.
The nitric acid reacts with other ions that might precipitate with silver nitrate. Doing this first gets these other unwanted precipitates out of the way. If you are testing with Fluoride as your halide remember that silver nitrate does not precipitate with Fluoride, so no precipitate does not mean that halide ions are not present.
halide ions strongly interact with the counter-ions. However, mineral oil is non-polar. To dissolve the halide ions (and the counter-ions) into mineral oil would drastically raise system energy. Thus it does not work. More simply, halide ions have a charge and won't easily dissolve in non-polar substances, since like-dissolves-like.
Ions of the halogen group are called halide ions; their compounds are called halides.
The presence of halide ions
They are generally represented as NaX. X shows the halide ion. The ions in this family are fluoride, chloride, bromide and iodide.
-1 oxidation state
When halogens form ions, they are called halide ions. These types of ions have a negative charge due to gaining electrons.
There are many of methods to test for "chemicals" in a molecular compound, you need to get more specific. i.e what "chemicals" we are looking for. For example if we have halide ions, to identify which halide ion is present add silver nitrate followed by ammonia solution. But theres always mass spectroscopy :p. There are may ways to test for "chemical". You need to be more specific. But theres spectroscopy. :p
detect nytrogen
A halide ion is a hydrogen atom with a negative charge.
No reaction occurs between the acidified hydrogen peroxide and the other halide ions, because the hydrogen ions involved in both cases are in the same group. For a reaction to occur it needed to have an element that is more reactive than hydrogen.
The Niritric acid is used to remove any ion without will contaminate the reaction. for example if there is any carbonate (CO3) then the nitric acid will react with it: 2 HNO3 (aq) & (CO3)-2 (aq) --> CO2 (g) & H2O (l) & 2 (NO3)- (aq)