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Rather than thinking of them as absorbers of heat, darker colors are better absorbers of light and thereby become better radiators of heat.

Consider the following:

The color of an object depends on the wavelengths of colors reflected from the object. A red apple is red because red wavelengths in white light are reflected and other wavelengths are absorbed. If a red apple were to be illuminated by light that had no red wavelengths, the apple would appear almost black.

When a black object is illuminated by white light, all wavelengths are absorbed and none are reflected -- that's why the object appears black. When light is absorbed by a black object, the energy carried by the light doesn't just disappear. Rather, it raises the energy of the object doing the absorbing. The object, in turn, releases the absorbed energy by emitting longer wavelength, lower energy infrared (heat). This transformation of light into heat is the key to understanding the process because it accounts for the law of conservation of energy. Light just doesn't disappear when it strikes a black object, it's transformed into another kind of radiation that is either radiated from or retained within the black object.

The darker the object, the better its emission of heat because, it is a better absorber of light.

http://www.newton.dep.anl.gov/askasci/phy00/phy00156.htm

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