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Polonium is a reactive metal but being very radioactive, dangerous, scarce and expensive the chemistry of Po was not intensively studied.
Some compounds of polonium are: PoO, PoO2, PoO3, PoH2, halides as PoX2, PoX4, PoX6 and the strange class of polonides (compounds of polonium with other metals). The Pauling electronegativity is 2. Possible valences are: 2, 4, 5, 6, -2.

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10y ago

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