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This is particularly true to metals, and are the basis for flame tests and even for flame AAS analysis. When a metal is heated, the energy is taken in, and this promotes an electron to the lowest unoccupied molecular orbital (LUMO). When this electron falls back down to the highest occupied molecular orbital (HOMO) the energy is often released as light, with a wavelength proportional to the energy difference between the HOMO and LUMO.

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Q: How is light produced when elements are heated to high temperatures?
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