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Let us find moles first.

Molarity = moles of solute/Liters of solution ( 750 ml = 0.750 Liters )

0.375 M Na2SO4 = moles Na2SO4/0.750 Liters

= 0.28125 moles Na2SO4

===================

0.28125 moles Na2SO4 (142.05 grams/1 mole Na2SO4)

= 39.95 grams Na2SO4 needed

---------------------------------------you do significant figures!

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