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First, you have to know what kind of sodium phosphate! Is it NaH2PO4, Na2HPO4, or Na3PO4?

In all three cases, the Na totally disassociates from rest of the molecule when you dissolve it in water. (And all are highly soluble in water.) Don't worry about the H atoms. They stay with the PO4.

The solution's molarity is 2 molar. (Note that "molarity" is NOT a unit.) That means there are 2 moles of sodium phosphate per liter.

500 mL is half a liter, therefore the sample has half of 2 moles of sodium phosphate. So, 1 mole of sodium phosphate.

Assuming you have NaH2PO4, then you have 1 mole of Na+ ions. For the other two chemicals, multiply by 2 or 3 as necessary.

I'm not telling you how to convert moles to numbers. If you can't do that, you should flunk chemistry.

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