16
S
Sulfur
32.065Atomic Number: 16
Atomic Weight: 32.065
Melting Point: 388.36 K (115.21°C or 239.38°F)
Boiling Point: 717.75 K (444.60°C or 832.28°F)
Density: 2.067 grams per cubic centimeter
Phase at Room Temperature: Solid
Element Classification: Non-metal
Period Number: 3 Group Number: 16 Group Name: Chalcogen
What's in a name? From the Sanskrit word sulvereand the Latin word sulphurium.
Say what? Sulfur is pronounced as SUL-fer.
History and Uses:
Sulfur, the tenth most abundant element in the universe, has been known since ancient times. Sometime around 1777, Antoine Lavoisier convinced the rest of the scientific community that sulfur was an element. Sulfur is a component of many common minerals, such as galena (PbS), gypsum (CaSO4·2(H2O), pyrite (FeS2), sphalerite (ZnS or FeS), cinnabar (HgS), stibnite (Sb2S3), epsomite (MgSO4·7(H2O)), celestite (SrSO4) and barite (BaSO4). Nearly 25% of the sulfur produced today is recovered from petroleum refining operations and as a byproduct of extracting other materials from sulfur containing ores. The majority of the sulfur produced today is obtained from underground deposits, usually found in conjunction with salt deposits, with a process known as the Frasch process.
Sulfur is a pale yellow, odorless and brittle material. It displays three allotropic forms: orthorhombic, monoclinic and amorphous. The orthorhombic form is the most stable form of sulfur. Monoclinic sulfur exists between the temperatures of 96°C and 119°C and reverts back to the orthorhombic form when cooled. Amorphous sulfur is formed when molten sulfur is quickly cooled. Amorphous sulfur is soft and elastic and eventually reverts back to the orthorhombic form.
Most of the sulfur that is produced is used in the manufacture of sulfuric acid (H2SO4). Large amounts of sulfuric acid, nearly 40 million tons, are used each year to make fertilizers, lead-acid batteries, and in many industrial processes. Smaller amounts of sulfur are used to vulcanize natural rubbers, as an insecticide (the Greek poet Homer mentioned "pest-averting sulphur" nearly 2,800 years ago!), in the manufacture of gunpowder and as a dying agent.
In addition to sulfuric acid, sulfur forms other interesting compounds. Hydrogen sulfide (H2S) is a gas that smells like rotten eggs. Sulfur dioxide (SO2), formed by burning sulfur in air, is used as a bleaching agent, solvent, disinfectant and as a refrigerant. When combined with water (H2O), sulfur dioxide forms sulfurous acid (H2SO3), a weak acid that is a major component of acid rain.
Estimated Crustal Abundance: 3.50×102 milligrams per kilogram
Estimated Oceanic Abundance: 9.05×102 milligrams per liter
Number of Stable Isotopes: 4 (View all isotope data)
Ionization Energy: 10.360 eV
Oxidation States: +6, +4, -2Electron Shell Configuration:
1s22s22p63s23p4
When aluminum and sulfur react, aluminum sulfide is produced.
Sulfur dioxide gas is produced when sulfur reacts with oxygen.
Sulfur + Oxygen -> Sulfur Dioxide
Sulfur dioxide (SO2) is produced by the reaction between sulfur (S) and oxygen (O2).
The equation for the burning of sulfur in the presence of oxygen to produce sulfur dioxide is: S (sulfur) + O2 (oxygen) --> SO2 (sulfur dioxide).
When aluminum and sulfur react, aluminum sulfide is produced.
Sulfur dioxide gas is produced when sulfur reacts with oxygen.
Sulfur + Oxygen -> Sulfur Dioxide
Sulfur dioxide (SO2) is produced by the reaction between sulfur (S) and oxygen (O2).
Sulfur dioxide is produced in a petrol engine when the fuel being burned contains sulfur impurities. As the fuel combusts, sulfur in the fuel reacts with oxygen in the air to form sulfur dioxide, which is then emitted as a pollutant in the exhaust gases of the engine.
When burning sulfur, sulfur dioxide gas is produced. This gas has a strong odor similar to burnt matches and can be harmful to human health and the environment.
Sulfur dioxide is produced by the burning of coal to produce electricity. Nearly 2/3 of the sulfur dioxide produced is through the burning of fossil fuels.
The equation for the burning of sulfur in the presence of oxygen to produce sulfur dioxide is: S (sulfur) + O2 (oxygen) --> SO2 (sulfur dioxide).
The balanced equation for the reaction of sulfur with oxygen to produce sulfur dioxide is: S + O₂ -> SO₂ From the reaction stoichiometry, 1 mole of sulfur produces 1 mole of sulfur dioxide. Therefore, the volume of sulfur dioxide produced would be 26.9 L.
Sulfur dioxide is typically produced by the burning of fossil fuels containing sulfur, such as coal and oil. It can also be released during volcanic eruptions and through certain industrial processes like metal smelting and paper production.
Sulfuric Acid is an oxoacid of sulfur and is made of Hydrogen, Sulfur and Oxygen. It is produced by burning sulfur in air to produce Sulfur Dioxide, and then oxidizing the Sulfur Dioxide to Sulfur Trioxide. Sulfuric Acid can then be made from Sulfur Trioxide.
If everything is under gaseous condition and with equal pressure and temperature, then also 4.0 L SO3 gas is produced from 4.0 L SO2,g.