Never heard about it but it is easy to find out the kind of hibridization if the ion exists.
valence electrons 42
central atom Cl (Extended octet)
four single bonds to F
one single coordinate bond or double bond to O
One non bonding pair
Total : need six equivalent orbitals to draw an octhaedric electronic geometry so hibridizate 1s 3p and 2d into 6 sp3d2 equivalent orbitals
Molecular geometry should be square pyramid
In molecular orbital theory, MO theory, molecular orbitals are "built" from atomic orbitals. A common approach is to take a linear combination of atomic orbitals (LCAO), specifically symmetry adapted linear combinations (SALC) using group theory. The formation of a bond is essentially down to the overlap of the orbitals, the orbitals being of similar energy and the atomic orbital wave functions having the correct symmetry.
True.
By the overlap of atomic orbitals. In valence bond theory these atomic orbitals may be s, p or d orbitals or "hybrids" such as sp3. This is a complex area and the above is a very simple explanation.
molecular orbital
overlapping that occurs along the orbital axis of 2 atomic orbitals is known as linear overlapping and these orbitals are called sigma atomic orbitals therefore these bonds are known as sigma bonds
sp2 hybrid orbitals overlap.
In molecular orbital theory, MO theory, molecular orbitals are "built" from atomic orbitals. A common approach is to take a linear combination of atomic orbitals (LCAO), specifically symmetry adapted linear combinations (SALC) using group theory. The formation of a bond is essentially down to the overlap of the orbitals, the orbitals being of similar energy and the atomic orbital wave functions having the correct symmetry.
True.
sigma, pi
By the overlap of atomic orbitals. In valence bond theory these atomic orbitals may be s, p or d orbitals or "hybrids" such as sp3. This is a complex area and the above is a very simple explanation.
molecular orbital
overlapping that occurs along the orbital axis of 2 atomic orbitals is known as linear overlapping and these orbitals are called sigma atomic orbitals therefore these bonds are known as sigma bonds
sp3 sp3 orbitals overlap Could you please explain why? :) Thank you!!
I2 then FICl IBr
Compare their atomic sizes; the bond strength is determined by the amount of "overlap" between their orbitals. What shapes give you the most overlap?
Covalent bonding does not necessarily require that the two atoms be of the there is good overlap between the atomic orbitals of participating atoms.
Double and triple bonds each have another type of bond different from the initial single bond present between the two bonded atoms. The sigma bond, the initial single bond, is formed through a head-on overlap of two atomic orbitals. Rotation about this bond does not change the overlap, and so rotation is allowed.But double and triple bonds have pi bonds, formed by side-on overlap between the atomic orbitals (typically either p or d orbitals). These bonds surround the sigma bond and were rotation to occur, the orbitals involved with the pi bonds would cease to overlap and these bonds would be broken.Therefore, the specific bond that restricts rotation about the axis of a double or triple bond would be the pi bond(s) involved.