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Al or Aluminium exists with metallic bonds, electrons are delocalised and in a "sea" which is electrostatically attracted to the positive proton.

Because they are free to move about and hence conduct a charge (the flow of charged particle's, be they electrons, protons or ions)

In KCL or Potassium Chloride the bonding is covalent where a pair of electrons are shared - resulting in each chemical be achieving a stable electron arrangement.

This stable electron arrangement is strong so the electrons are not free to move about - meaning that KCl will not conduct well.

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