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The definition of an acid is commonly known as a substance which can produce hydrogen ions (Hydronium ions to be more precise) in solution. However, the currently more 'correct definition' of an acid is the Bronsted-Lowry definition which states that an acid is a substance which donates protons (i.e. hydrogen ions).

Carbonic acid, as the name implies, is an acid which can ionise in aqueous solution to form bi-carbonate ions and hydrogen ions. In other words, carbonic acid ionises in solution to give up a proton (hydrogen ion) and produce bi-carbonate ions.

H2C03 <-> H+ + HCO3-

However, bicarbonate ions can act as a base or an acid according to Bronsted-Lowry definition as bi-carbonate ions can accept or donate protons (hydrogen ions). We call these substances which can accept or donate protons: Amphiprotic substances. Thus, bicarbonate ion is an amphiprotic substance because it can act a either a base or an acid.

Bi-carbonate ions acting as an acid:

HCO3- <-> H+ + CO32-

Bi-carbonate ions acting as an base:

HCO3- + H+ <-> H2CO3

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