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Only free, dissolved hydroxides of alkali and earth alkali metals are strong because (OH-)aq is a strong base only if it is a free ion in water.

Iron is a (polyvalent) transition metal of which the hydroxides are (partially) non-dissolvable and can form mixed hydrate complex ions (e.g. Fe(OH)3(H2O) ).

It is both a weak base and a weak acid!! (all reactions are equilibrium reactions of protolysis)

  • basic:

    Fe(OH)3(H2O) + H3O+ <=> Fe+(OH)2(H2O)2 + H2O

    or

    Fe(OH)3(H2O) + H2O <=> Fe+(OH)2(H2O)2 + OH-

  • acidic:

    Fe(OH)3(H2O) + OH- <=> Fe(OH)4- + H2O

    or

    Fe(OH)3(H2O) + H2O <=> Fe(OH)4-+ H3O+

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