In order to convert KMnO4 to K2MnO4, a reducing agent is typically needed. One common method involves using a reducing agent like a metal, such as zinc or iron, to react with KMnO4 in an acidic medium to produce K2MnO4.
here is the rection... 2KMnO4 + 3H2SO4 = K2SO4 + 2MnSO4 + 3H2O + 2.5O2 (alkaline) and in other conditions... 6 KMnO4 + 9 H2SO4 → 6 MnSO4 + 3 K2SO4 + 9 H2O + 5 O3 The H2SO4/KMnO4 reaction can also produce the oily Mn2O7, which is unstable and can decompose explosively.
The ratio of equivalent weight of KMnO4 in acidic to basic medium is 1:2:5. In acidic medium, KMnO4 reacts as MnO4^- + 8H+ + 5e^- → Mn^2+ + 4H2O, requiring 5 equivalents, whereas in basic medium, it reacts as MnO4^- + 2H2O + 3e^- → MnO2 + 4OH^-, requiring 2 equivalents. In neutral medium, the equivalent weight is the same as in basic medium.
The oxidation number of Mn in KMnO4 is +7. This can be determined by assigning the known oxidation numbers of potassium (+1) and oxygen (-2) and solving for the unknown oxidation number of manganese.
Manganese can be oxidized all the way up to +7, so conceivably 6 K2MnO4 +O3 -> 3 K20 + 6 KMnO4 is possible. However the most stable oxidation state of Manganese is +2 so you would have to 'hit it pretty hard' with a lot of energy to get it all the way up to +7.
H2SO4 is typically used instead of HCl in the titration of KMnO4 because HCl can react with KMnO4 and form chlorine gas, which can interfere with the titration results. Additionally, H2SO4 provides the required acidic medium for the reaction to occur between KMnO4 and the analyte.
Equivalent weight of KMnO4 is equal with molar weight of KMnO4. The some is and for K2MnO4, K2MnO4 - e +OH- --------- KMnO4 + KOH In general, Equivalent weight = Molar weight / Number of electrons that take or give one molecule Equivalent weight of KMnO4 = Molar weight of KMnO4 / 1
The empirical formula for potassium manganate is KMnO4.
At low pH value this decomposition takes place: 3 K2MnO4 + 2 H2O → 2 KMnO4 + MnO2 + 4 KOH
here is the rection... 2KMnO4 + 3H2SO4 = K2SO4 + 2MnSO4 + 3H2O + 2.5O2 (alkaline) and in other conditions... 6 KMnO4 + 9 H2SO4 → 6 MnSO4 + 3 K2SO4 + 9 H2O + 5 O3 The H2SO4/KMnO4 reaction can also produce the oily Mn2O7, which is unstable and can decompose explosively.
Among the compounds listed, potassium permanganate (KMnO4) is the strongest oxidizing agent. It can readily donate oxygen atoms in reaction with other substances, making it a powerful oxidizing agent in various chemical processes.
Potassium manganate = K2MnO4 Potassium permanganate = KMnO4 It is important to quote the oxidation state of the compound. Potassium manganate could easily be potassium manganate (VI) as opposed to potassium manganate (VII) KMnO4 Potassium manganate (VI) K2MnO4 is a dark green compound made by fusing manganese (IV) oxide with potassium hydroxide. It is stable in basic solution In aqueous acidic solution it disproportionates to the manganate (VII) ion and manganese (IV) oxide.
The ratio of equivalent weight of KMnO4 in acidic to basic medium is 1:2:5. In acidic medium, KMnO4 reacts as MnO4^- + 8H+ + 5e^- → Mn^2+ + 4H2O, requiring 5 equivalents, whereas in basic medium, it reacts as MnO4^- + 2H2O + 3e^- → MnO2 + 4OH^-, requiring 2 equivalents. In neutral medium, the equivalent weight is the same as in basic medium.
The oxidation number of Mn in KMnO4 is +7. This can be determined by assigning the known oxidation numbers of potassium (+1) and oxygen (-2) and solving for the unknown oxidation number of manganese.
Manganese can be oxidized all the way up to +7, so conceivably 6 K2MnO4 +O3 -> 3 K20 + 6 KMnO4 is possible. However the most stable oxidation state of Manganese is +2 so you would have to 'hit it pretty hard' with a lot of energy to get it all the way up to +7.
The compound name for K2MnO4 is potassium permanganate.
H2SO4 is typically used instead of HCl in the titration of KMnO4 because HCl can react with KMnO4 and form chlorine gas, which can interfere with the titration results. Additionally, H2SO4 provides the required acidic medium for the reaction to occur between KMnO4 and the analyte.
Acid is added in KMnO4 titration to provide an acidic medium, which helps to stabilize the oxidizing agent MnO4-. The acidic solution also helps to prevent the premature reduction of permanganate ions and ensures a clear endpoint in the titration by facilitating the reaction with the analyte.