A disproportionation reaction is one in which a species has been both oxidised and reduced (that is, the oxidation state of the related species found in the products has increased in one instance, and decreased in another, in relation to that of the species found in the reactants).
The classic example of disproportionation is the reaction between chlorine gas and dilute sodium hydroxide, although there are many others:
Cl2 + 2NaOH --> H2O + NaCl + NaClO
The oxidation state of chlorine is 0 in the reactants, but has decreased to -1 in NaCl AND has increased to +1 in sodium chlorate, NaClO.
The disproportionation of hydrogen peroxide is represented by the following reaction: 2H2O2 - 2H2O O2
ClO2- shows a disproportionation reaction because in this species, the oxidation state of chlorine is in between -1 (in Cl-) and +4 (in ClO4-), which allows for both oxidation and reduction to occur in the same compound. ClO4- does not undergo disproportionation as the oxidation state of chlorine is already at its highest state, +7, making further oxidation not possible.
Dimeric selenium chloride (Se2Cl2) undergoes disproportionation reaction in the presence of water to form selenious acid (H2SeO3) and hydrochloric acid (HCl). This reaction involves the reduction of Se4+ in Se2Cl2 to Se2+ in H2SeO3 and the oxidation of Se4+ to Se6+ in HCl by water.
A "decomposition" or "disproportionation" reaction.
another name for an exchange reaction but metathesis reaction. This reaction usually occurs in hydrolysis and is AB+CD=AD+CB
The disproportionation of hydrogen peroxide is represented by the following reaction: 2H2O2 - 2H2O O2
A Cannizzaro reaction is the disproportionation of an aldehyde into an alcohol and carboxylic acid.
The Cannizzaro reaction involving glyoxal is a self-disproportionation reaction where two molecules of glyoxal react to form one molecule of glyoxalic acid and one molecule of glyoxylic acid. This reaction is a type of redox disproportionation reaction, where one molecule is oxidized and the other is reduced simultaneously. Glyoxal is a dialdehyde compound that readily undergoes this disproportionation reaction in alkaline conditions.
It is called disproportionation. In this type of reaction, an element undergoes both oxidation and reduction, leading to the formation of two different oxidation states of the element.
A Cannizzaro reaction is the disproportionation of an aldehyde into an alcohol and carboxylic acid. The Cannizzaro reaction, named after its discoverer Stanislao Cannizzaro, is a chemical reaction that involves the base-induced disproportionation of two molecules of a non-enolizable aldehyde to give a primary alcohol and a carboxylic acid. Named after: Stanislao Cannizzaro
ClO2- shows a disproportionation reaction because in this species, the oxidation state of chlorine is in between -1 (in Cl-) and +4 (in ClO4-), which allows for both oxidation and reduction to occur in the same compound. ClO4- does not undergo disproportionation as the oxidation state of chlorine is already at its highest state, +7, making further oxidation not possible.
Dimeric selenium chloride (Se2Cl2) undergoes disproportionation reaction in the presence of water to form selenious acid (H2SeO3) and hydrochloric acid (HCl). This reaction involves the reduction of Se4+ in Se2Cl2 to Se2+ in H2SeO3 and the oxidation of Se4+ to Se6+ in HCl by water.
A "decomposition" or "disproportionation" reaction.
another name for an exchange reaction but metathesis reaction. This reaction usually occurs in hydrolysis and is AB+CD=AD+CB
This is a thermal decomposition reaction.
6CrO2 (aq) + 10 H+ (aq) --> Cr O72- (aq) + 4 Cr3+ (aq) + 5H2O (l)
Ketones do not undergo the Cannizzaro reaction because they lack an alpha hydrogen atom, which is essential for the reaction to proceed. The Cannizzaro reaction involves the disproportionation of aldehydes in the presence of a strong base, where one molecule is oxidized to a carboxylic acid and another is reduced to an alcohol. Since ketones are generally more stable and do not possess the necessary alpha hydrogen, they do not participate in this reaction. Instead, ketones typically undergo other reactions, such as nucleophilic addition.