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What kind of enthalpy change favors a spontaneous reaction?
For a spontaneous reaction, the overall change in enthalpy should be negative (exothermic). This means that the products have a lower enthalpy than the reactants, releasing energy in the form of heat.
What could make delta G become negative at a given enthalpy and entropy?
For delta G to become negative at a given enthalpy and entropy, the process must be spontaneous. This can happen when the increase in entropy is large enough to overcome the positive enthalpy, leading to a negative overall Gibbs free energy. This typically occurs at higher temperatures where entropy effects dominate.
Why you measure enthalpy in H instead of H?
The total enthalpy of a system is called "H." That stands for "total enthalpy." It is not a measure of enthalpy. Enthalpy is measured in the SI or metric system in joules (abbreviated as J) or in customary units such as British Thermal Unit (BTU) or calories (cal).
What is the significance of a negative enthalpy change in a chemical reaction?
A negative enthalpy change in a chemical reaction indicates that the reaction is exothermic, meaning it releases heat energy to the surroundings. This is significant because it shows that the reaction is giving off energy rather than absorbing it, which can affect the temperature and overall energy balance of the system.
How do you calculate the enthalpy of formation for a chemical compound?
To calculate the enthalpy of formation for a chemical compound, you subtract the enthalpies of formation of the reactants from the enthalpies of formation of the products. This gives you the overall change in enthalpy for the reaction, which represents the enthalpy of formation for the compound.
What kind of enthalpy change favors a spontaneous reaction?
For a spontaneous reaction, the overall change in enthalpy should be negative (exothermic). This means that the products have a lower enthalpy than the reactants, releasing energy in the form of heat.
How do you know if an enthalpy change diagram is endothermic or exothermic?
If you plot the reaction coordinate (what I think you mean by "enthalpy change diagram"), the reaction will be exothermic if the products are lower on the graph than the reactants. If they are higher than it is endothermic. For instance, if you go to the linked Wikipedia page (link to the left of this answer), the graph shown is of an exothermic reaction.
What type of reaction is exothermic reaction?
The reaction in which energy is being released, and the overall energy change (enthalpy) is negative.
Predict whether the changes in enthalpy entropy and free energy will be positive or negative for the freezing of water and explain your predictions How does temperature affect the spontaneity?
The changes in enthalpy, entropy, and free energy are negative for the freezing of water since energy is released as heat during the process. At lower temperatures, the freezing of water is more spontaneous as the negative change in enthalpy dominates over the positive change in entropy, making the overall change in free energy negative and leading to a spontaneous process.
What could make delta G become negative at a given enthalpy and entropy?
For delta G to become negative at a given enthalpy and entropy, the process must be spontaneous. This can happen when the increase in entropy is large enough to overcome the positive enthalpy, leading to a negative overall Gibbs free energy. This typically occurs at higher temperatures where entropy effects dominate.
Why you measure enthalpy in H instead of H?
The total enthalpy of a system is called "H." That stands for "total enthalpy." It is not a measure of enthalpy. Enthalpy is measured in the SI or metric system in joules (abbreviated as J) or in customary units such as British Thermal Unit (BTU) or calories (cal).
What is the significance of a negative enthalpy change in a chemical reaction?
A negative enthalpy change in a chemical reaction indicates that the reaction is exothermic, meaning it releases heat energy to the surroundings. This is significant because it shows that the reaction is giving off energy rather than absorbing it, which can affect the temperature and overall energy balance of the system.
What is relation between hydration energy lattice energy and enthalpy of solution?
The enthalpy of solution is the sum of the lattice energy (energy required to break apart the crystal lattice) and the hydration energy (energy released when ions are solvated by water). If the final enthalpy of solution is negative, it indicates that the overall process is exothermic and favors dissolution in water. Conversely, a positive enthalpy of solution implies that the process is endothermic and less likely to occur spontaneously.
How do you calculate the enthalpy of formation for a chemical compound?
To calculate the enthalpy of formation for a chemical compound, you subtract the enthalpies of formation of the reactants from the enthalpies of formation of the products. This gives you the overall change in enthalpy for the reaction, which represents the enthalpy of formation for the compound.
Does the overall enthalpy change of a chemical reaction depend on the reaction pathway?
No, the overall enthalpy change of a chemical reaction is independent of the reaction pathway. This is because enthalpy is a state function, meaning it only depends on the initial and final states of the system, not on how the system reached those states.
How does the enthalpy temperature dependence affect the overall energy changes in a chemical reaction?
The enthalpy temperature dependence influences the overall energy changes in a chemical reaction by affecting the heat absorbed or released during the reaction. As temperature increases, the enthalpy change also changes, which can impact the reaction's energy balance.
What is the significance of the sign of enthalpy change in chemical reactions?
The sign of the enthalpy change in a chemical reaction indicates whether the reaction is exothermic (negative sign) or endothermic (positive sign). This is important because it tells us if heat is being released or absorbed during the reaction, which can affect the overall energy balance of the system.
