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The sucrose van 't Hoff factor affects colligative properties in solutions by determining the number of particles that contribute to those properties. The van 't Hoff factor for sucrose is 1 because it does not dissociate into ions in solution, unlike salts that dissociate into multiple ions. This means that sucrose does not affect colligative properties as much as salts do, which can lower the freezing point and raise the boiling point of a solution.

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