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Short answer: See [for a polar example] the molecule Water, H2O: occasionally it will 'disassociate' into the H+ and the OH- IONS, yet mostly it exists as an electrically neutral H2O. As in reality, the two H+'s are on one end of the molecule while the other end of the molecule is occupied by the electronegative oxygen atom, so two H+ & one O 2- make up a neutral atom that is electrically active at its ends, or poles; or polar.

Nonpolar? Remove oxygen; leave just carbon and hydrogen, which provides a balanced or nonpolar [if any] charge distribution.

Do Not Separate the two, Tao says no. What gives Lipids (plain oils -from plants- and fats -from animals-, phospholipids, glycolipids etc.) their great powers is that they possess a polar [or charged by the presence of an acid group - COO- ] hydrophillic head AND a neutral [no charges] non polar ( only CH2 s ) hydrophobic tail.

This is why lipids are also known as fatty-acids.

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