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The OH group bonding with the carbonyl group has a pKa around 5, and the OH group connected ortho of the carbonyl group has a pKa around 10.

Added correction:

Salicylic acid is a monoprotic, not a diprotic acid in water.

From wikipedia table value: pKa 2.97

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10y ago
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10y ago

The -COOH (carboxylic acid) and the -OH (phenolic) hydrogens

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Q: What are the acidic hydrogens in salicylic acid?
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Is salicylic acid acidic basic or neutral?

It is slightly basic. Behaves almost completely neutral.


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