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CaCO3 + 2 HCl = CaCl2 + CO2 + H2O

Calcium Carbonate + 2 Hydrochloric Acid = Calcium Chloride + Carbon Dioxide(which is a gas) + Water

CaCO3 + 2 CH3COOH = Ca(CH3COO)2 + CO2 + H2O

Calcium Carbonate + 2 Acetic Acid (Vinegar) = Calcium Acetate + Carbon Dioxide + Water

In these equations it is obvious that Carbon Dioxide is mostly released after an reaction of calcium carbonate with some acids.

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