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With a solution of acetic acid (ethanoic acid) the vinegar solution and the limestone (calcium carbonate) will undergo the following reaction:

2 CH3COOH + CaCO3 (CH3COO)2Ca + CO2 +H2O

So the products are a salt : Calcium Ethanoate ( this could be extracted by evaporation), the co-products are carbon dioxide ( a gas which causes the solution/substance to effervesce as it is produced) and finally water is also produced.

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