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.0821 is the constant in the ideal gas formula (PV=nRT , R being the constant). The units for .0821 are

(atm)(L) over (mols)(kelvin).

So if you were to use it in a calculation, it would look something like:

(1atm)(22.4L)=(1mol)(.0821 atmL/molsKelvin)(273K)

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